EPOXIDIZED SOYABEAN OIL (SECONDARY PLASTICIZER) USED IN PVC COMPOUND

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Epoxidized soybean oil, better known by its acronym, ESBO, is a plasticizer used in polyvinyl chloride (PVC) plastics. It serves as a plasticizer and as a scavenger for hydrochloric acid liberated from PVC when the PVC undergoes heat treatment.

A few EU surveys have shown fairly high levels of ESBO in foods, in which about 4% were above the current specific migration limit (SML) for ESBO of 60 mg/kg and about 15% of the samples were above 30 mg ESBO/kg food. High migration levels might lead to an intake that exceeds the existing Tolerable Daily Intake of 1 mg/kg body weight/day.

Epoxidized linolein a major component of ESBO

ESBO is manufactured from soybean oil through the process of epoxidation. The reason why vegetable oils are widely used as plasticizers is because the high numbers of carbon-carbon double bonds present in vegetable oils make them a good target for manipulation into some other useful products like in this case – from soybean oil into epoxidized soybean oil. The epoxide group is more reactive than double bond, thus providing a more energetically favorable site for reaction and making the oil a good hydrochloric acid scavenger and plasticizer. Usually a peroxide or a peracid is used to add an atom of oxygen and convert the -C=C- bond to an epoxide group.

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Description

INTRODUCTION
EPOXIDIZED LINOLEIN A MAJOR COMPONENT OF ESBO
PROPERTIES AND CHARACTERISTICS OF EPOXIDIZED SOYABEAN OIL
STRUCTURE, COMPOSITION AND PROPERTIES OF VEGETABLE OILS
1) COMPOSITION AND PROPERTIES
CHEMICAL STRUCTURE OF COMMON FATTY ACID
CHEMICAL COMPOSITION OF VEGETABLE OIL
CHEMICAL COMPOSITION OF VEGETABLE OIL
PROPERTIES OF VEGETABLE OIL
USES AND APPLICATION
APPLICATIONS
TOXICITY OF EPOXIDIZED SOYABEAN OIL
FOOD SAFETY AND LEGISLATION FOR EPOXIDIZED SOYABEAN OIL
LEGISLATION
B.I.S. SPECIFICATION
GRADE OF EPOXIDIZED SOYA BEAN OIL
MARKET SCENARIO OF PLASTICIZER
FIGURE: MARKET SHARE OF PLASTICIZERS IN VARIOUS APPLICATIONS
GLOBAL MARKET TRENDS OF PLASTICIZER
FIGURE: MARKET SHARE OF DIFFERENT PLASTICIZERS IN MMT/ANNUM
GLOBAL MARKET TRENDS OF DOP
GLOBAL KEY PLAYERS
REGIONAL MARKET TRENDS
FIGURE: REGIONAL MARKET SHARE OF PLASTICIZER
FIGURE: MARKET SHARE OF VARIOUS PLASTICIZER IN USA
FIGURE: MARKET SHARE OF VARIOUS PLASTICIZER IN EUROPE
FIGURE: MARKET SHARE OF VARIOUS PLASTICIZER IN ASIA
THE FOLLOWING PIE CHART SHOWS WORLD CONSUMPTION
OF PLASTICIZERS:
INDIAN MARKET TRENDS
INDIAN INSTALLED CAPACITY
OUTLOOK
MARKET SURVEY
THE EPOXIDIZED SOYBEAN OIL MARKET IS ESTIMATED TO HIT
$360.6 MILLION BY 2023
MARKET SEGMENTATION: GLOBAL EPOXIDIZED SOYBEAN OIL MARKET
GLOBAL OVERVIEW OF PVC MARKET
INDIAN PVC MARKET
PRESENT MANUFACTURES AND SUPPLIERS OF EPOZIDIZED SOYABEAN OIL
FORMULATION OF EPOXIDIZED SOYABEAN OIL
MANUFACUTRING PROCESS OF EPOXIDIZED SOYABEAN OIL
(SECONDARY PLASTICIZER) USED IN PVC COMPOUND
EPOXIDATION OF SOYBEAN OIL TO OBTAIN
EPOXIDIZED SOYABEAN OIL (ESBO)
PROCESS DESCRIPTION FOR EPOXIDATION OF SOYABEAN OIL
SAFETY CRITERIA FOR THE EPOXIDATION OF SOYABEAN OIL
SAFETY CRITERIA
REACTION SCHEME OF EPOXIDATION PROCESS
REACTION SCHEME
SCHEME OF THE EPOXIDATION REACTIONS.
MASS AND ENERGY EQUATIONS
PROCESS FLOW DIAGRAM OF EPOXIDIZED SOYABEAN OIL
(SECONDARY PLASTICIZER) USED IN PVC COMPOUND
TESTING PROCEDUSE FOR EPOXIDIZED SOYABEAN OIL
ANALYTICAL METHODS
TITRATION OF EPOXY (OXIRANE OXYGEN)
FTIR SPECTRUM
EPOXY CONTENTS OF ESO
FTIR OF TRIGLYCERIDES AND EPOXIDIZED TRIGLYCERIDES
DIFFERENT METHOD OD EPOXIDATION
ESTABLISHED METHODS OF EPOXIDATION ARE AS FOLLOWS:
CONVENTIONAL CHEMICAL TREATMENT
II) ACID ION EXCHANGE RESIN (AIER) METHOD
III) ENZYMATIC METHOD
IV) METAL CATALYST METHOD
PROCESS INTENSIFICATION AND KINETICS FOR EPOXIDATION
OF SOYABEAN OIL
TABLE 1: KINETIC EXPRESSION, KINETIC LAWS AND ACTIVATION ENERGY.
REACTION MECHANISM AND KINETICS OF EPOXIDATION
REACTION MECHANISM
KINETICS OF EPOXIDATION
THERMODYNAMIC PROPERTIES OF THE EPOXIDIZED VEGETABLE OIL
CONTINUOUS EPOXIDATION FLOW PROCESS
VEGETABLE OIL
PHASE-TRANSFER CATALYSED EPOXIDATION OF SOYABEAN OIL USING
HYDROGEN PEROXIDE AND SUPERCRITICAL CARBON DIOXIDE
MATERIAL SAFETY DATA SHEET
CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
HAZARD(S) IDENTIFICATION
COMPOSITION / INFORMATION ON INGREDIENTS
FIRST AID MEASURES
FIRE-FIGHTING MEASURES
ACCIDENTAL RELEASE MEASURES
HANDLING AND STORAGE:
EXPOSURE CONTROLS / PERSONAL PROTECTION
PHYSICAL AND CHEMICAL PROPERTIES
TOXICOLOGICAL INFORMATION
PLANT LAYOUT
SUPPLIERS OF RAW MATERIALS
ACETIC ACID
HYDROGEN PEROXIDE
SULPHURIC ACID
SUPPLIERS OF PLANT AND MACHINERIES
BOILERS
REACTORS
OIL STORAGE TANK
OIL PACKAGING MACHINE
FILTER PRESS

APPENDIX – A:

1. COST OF PLANT ECONOMICS
2. LAND & BUILDING
3. PLANT AND MACHINERY
4. FIXED CAPITAL INVESTMENT
5. RAW MATERIAL
6. SALARY AND WAGES
7. UTILITIES AND OVERHEADS
8. TOTAL WORKING CAPITAL
9. COST OF PRODUCTION
10. PROFITABILITY ANALYSIS
11. BREAK EVEN POINT
12. RESOURCES OF FINANCE
13. INTEREST CHART
14. DEPRECIATION CHART
15. CASH FLOW STATEMENT
16. PROJECTED BALANCE SHEET

Additional information

Plant Capacity

12.00 MT./day
Land and Building

(4000 Sq.Mtr)
Plant & Machinery

US$. 230000
Rate of Return

42%
Break Even Point

41%

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